Refer to the solubility curves given in the graph provided below. If equal masses of hot, saturated solutions of compounds 'A' and 'B' are cooled from 80 °C to 60 °C, which solution is likely to deposit more solid? [Pg. No. 79]

Compound B solution is likely to deposit more solid.
From the graph, when the temperature is lowered from 80 °C to 60 °C, the solubility of compound B decreases much more sharply than that of compound A. Compound A shows only a small decrease in solubility, so only a small amount of solid will separate out. Since a hot saturated solution contains the maximum solute at 80 °C, cooling reduces its solubility, and the excess solute crystallises out. Therefore, the saturated solution of compound B will deposit more solid on cooling.